When there are more than two charges, we use this principle of superposition to get the effective force experienced by the a single charge due to presence of all the remaining charges.
According to the principle of superposition, the total effective force exerted on a given charge is the vector sum of all the individual forces that various charges exert seperately on the given charge
Let us consider charges q1,q2,q3..........qn kept stationary at different points. Let the force exerted on q1 by q2 is F12 the force assumed to be independent of other charges(in calculating the F12 we neglect the presence of all other charges excepting q1 and q2)
Similarly let the force exerted on q1 by q3 is F13..........and force on q1 by qn is F1n
Then the total effective force on q1 is given by
F=F12+F13+F14+.......+F1n
The force F12 can be directly calculated by Coulomb's law.